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Chimie moléculaire Paris Centre
ÉCOLE DOCTORALE 406

Polyaromatic-adorned N-Heterocyclic Carbenes. From Homogeneous Catalysis to Host-guest chemistry studies

Séminaire du Prof Eduardo Peris (Instituto de Materiales Avanzados (INAM) Universitat Jaume I.)

Abstract :

In the course of our most recent research, we demonstrated how homogeneous catalysts with polyaromatic functionalities possess properties that clearly differ from those shown by analogues lacking these polyaromatic systems. The differences arise from the ability of the polyaromatic groups to afford non-covalent interactions with aromatic molecules, which can either be substrates in a homogeneous catalysed reaction, or the same catalysts to afford self-assembled systems.

We also prepared a large variety of metallo-supramolecular complexes, including metallotweezers, metallo-rectangles, metallo-folders and bowl-shaped metallo-structures. Depending on their structural features, these species were used for the recognition of a variety of organic substrates, such as electron-deficient aromatic substrates, polycyclic aromatic hydrocarbons and heavy metal cations. The most relevant results in this research will be presented.

15/03/19

Traductions :

    Contact

    Directeur

    cyril.ollivier@sorbonne-universite.fr (cyril.ollivier @ upmc.fr)

     

    Directeur adjoint

     

     

    Secrétariat

    Irène Rasoarinoro (irene.rasoarinoro @ upmc.fr)

    Tel. : 01 44 27 38 48

     

    SU - ED 406

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    BC 63 - 4 Place Jussieu 

    75252 Paris cedex 5