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Chimie moléculaire Paris Centre
ÉCOLE DOCTORALE 406

Organometallic chemistry of low-valent lanthanides: unusual oxidation states and magnetic sandwiches

Séminaire du Dr Grégory Nocton (Ecole Polytechnique)

Abstract :

Organolanthanide complexes are an interesting class of organometallic compounds that have been developed in the 1950’s and that now concern most of the rare earths in their trivalent and divalent states. The applications for such compounds are numerous for single electron transfer reactivity and also because of their optical and magnetic properties: their Single-Molecule-Magnet behavior have impressed with record blocking temperatures. We will present a short overview of our methodology for the synthesis of organometallic complexes with very original geometry and in which the oxidation state is not trivial to assess because of the development of multiconfigurational electronic states.

02/03/20

Traductions :

    Contact

    Directeur

    Dr Cyril OLLIVIER (cyril.ollivier @ upmc.fr)

     

    Directeur adjoint PSL

    Dr Fethi BEDIOUI (fethi.bedioui @ chimieparistech.psl.eu)

     

    Secrétariat

    Irène RASOARINORO  (irene.rasoarinoro @ upmc.fr)

    Tel. : 01 44 27 38 48

     

    SU - ED 406

    Tour 32 - 42

    Bureau 114 (1er étage)

    BC 63 - 4 Place Jussieu 

    75252 Paris cedex 5