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Chimie moléculaire Paris Centre

Non-Precious Metal-Catalyzed Oxidant Free (De)-hydrogenation of Alcohols for Organic Transformations

Séminaire du Dr Debasis Banerjee (Indian Institute of Technology Roorkee, India)

Abstract :

Recently, there is a potential drive to replace the precious noble-metal catalysts using earth abundant and inexpensive non-noble metals for sustainable organic transformations. We have studied the applications of Ni-, Fe- and Mn-based catalysts for selective construction of amines, amides, five or six-membered N-heterocycles, activation of weak sp3 C-H bond, E-selective olefins and functionalization of ketone enolates. A detailed mechanistic and kinetics studies were also established for such transformations.


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