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Chimie moléculaire Paris Centre
ÉCOLE DOCTORALE 406

Asymmetric Catalysis Induced by Visible Light: From Free Radical to Excited State Chemistry

Séminaire du Pr Eric Meggers (Department of Chemistry, University of Marburg)

Abstract

The lecture will report on our progress to intertwine visible-light-activated chemistry with asymmetric catalysis. An unusual class of catalystis is employed which derive their chirality exclusively from a stereogenic metal center. Bis-cyclometalated chiral-at-metal iridium(III) and rhodium(III) catalysts provide substrate activation and the asymmetric induction, and often simultaneously serve as photoactive species (typically after substrate binding) for photoredox-mediated free radical chemistry or even direct bond forming reactions from photoexcited states.

26/09/17

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    Contact

    Directrice 

    Anna Proust (anna.proust @ upmc.fr)

     

    Directeur adjoint

    Matthieu Sollogoub (matthieu.sollogoub @ upmc.fr)

     

    Secrétariat

    Irène Rasoarinoro (irene.rasoarinoro @ upmc.fr)

    Tel. : 01 44 27 38 48

     

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